Deuterium substitution and solvent effects on reaction dynamics in extended-nano spaces on a chip

Takehiko Tsukahara; Kyosuke Nagaoka; Takehiko Kitamori

Conference paper

Deuterium substitution and solvent effects on reaction dynamics in extended-nano spaces on a chip

Takehiko Tsukahara, Kyosuke Nagaoka and Takehiko Kitamori

12th International Conference on Miniaturized Systems for Chemistry and Life Sciences - The Proceedings of MicroTAS 2008 Conference, pp.1537-1539

2008

Appears in keyword about Chemistry

Abstract

Extended-nano

NMR relaxation

Proton transfer

Tautomeric

Chemical Engineering (miscellaneous)

Bioengineering

We have investigated deuterium-substitution and solvent effects for the keto-enol tautomerization of acetylacetone (Hacac) confined in 10 - 100 nm scale spaces (called extended-nano spaces) based on NMR spectroscopic results, and elucidated the tautomeric reaction mechanisms in the extended-nano spaces.

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Title: Deuterium substitution and solvent effects on reaction dynamics in extended-nano spaces on a chip
Translated title: Deuterium substitution and solvent effects on reaction dynamics in extended-nano spaces on a chip
Creators - without role: Takehiko Tsukahara - RLNR, Tokyo Institute of Technology
Kyosuke Nagaoka - Department of Applied Chemistry, School of Engineering, University of Tokyo
Takehiko Kitamori - Department of Applied Chemistry, School of Engineering, University of Tokyo
Publication Details: 12th International Conference on Miniaturized Systems for Chemistry and Life Sciences - The Proceedings of MicroTAS 2008 Conference, pp.1537-1539
Identifiers: 9957775310106774
Academic Unit: Institute of NanoEngineering and Microsystems, College of Engineering, National Tsing Hua University
Language: English
Resource Type: Conference paper

Deuterium substitution and solvent effects on reaction dynamics in extended-nano spaces on a chip

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