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High efficient femtoliter reversed phase chromatography in a 10 mm extended-nanochannel for amino acids analysis
Conference paper

High efficient femtoliter reversed phase chromatography in a 10 mm extended-nanochannel for amino acids analysis

A. Smirnova, H. Shimizu, K. Mawatari and T. Kitamori
MicroTAS 2015 - 19th International Conference on Miniaturized Systems for Chemistry and Life Sciences, pp.1951-1953
2015

Abstract

Amino acids separation Extended-nano space Microchip RP-HPLC Control and Systems Engineering
In this paper we successfully fabricated a microchip with wide and long (800 nm hydrodynamic diameter and 10 mm length) extended-nano channel and realized the reversed phase liquid chromatography separation of amino acids after octadecylsilylation (ODS). The separation performance characteristics were obtained. The permeability of this nanochannel (K= 47×10 m ) is comparable with that of monolithic column, also it exhibit very low separation impedance (E = 13). Plate number counts were 4000 and plate height was 2.5 um. Due to its size this channel can be applied for macromolecules separation (proteomics).

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