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Ultra-low detection-limit heavy metal ion detection via electrochemical enhanced porous silicon photonic sensors
Conference paper

Ultra-low detection-limit heavy metal ion detection via electrochemical enhanced porous silicon photonic sensors

Ken-Hua Chih, Wan-Ting Tsai, Jain-Ren Lai, Minh-Hang Nguyen, Hai-Binh Nguyen, Ming-Chang Lee and Fan-Gang Tseng
21st International Conference on Miniaturized Systems for Chemistry and Life Sciences, MicroTAS 2017, pp.481-482
2020

Abstract

Bragg reflectors Electrochemical reduction Heavy metal ion detection RI sensor Chemical Engineering (miscellaneous) Bioengineering
In this paper, we propose an ultra-low detection limit silicon photonic sensors based on one dimensional microcavity structures with electrochemical signal enhancement for heavy metal ion detection in water. The 1-D microcavity [1] consists of two distributed Bragg reflectors (DBR) symmetrically placed about a defect layer fabricated by successive electrochemical etchings (ECE). It detects Cd 2+ concentration by the characteristic peak shift in the spectrum due to different concentrations of the ions in liquid or refraction index, RI, variation [2], and the detection limit now can approach 1 ppb by the enhancement of electrochemical reduction process, not only 10 5 times more sensitive than before but also with a EC specific selectivity for the target ions simultaneously.

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