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Hexagonal boron nitride coated carbon nanotubes:interlayer polarization improved field emission
Dissertation

Hexagonal boron nitride coated carbon nanotubes:interlayer polarization improved field emission

Chang, Han Chen
Doctor of Philosophy (PHD), 國立清華大學, 材料科學工程學系
2014

Abstract

奈米碳管 場發射 氮化硼 界面極化 Carbon nanotube Field emission Boron nitride Interlayer polarization
Carbon nanotubes (CNTs) which have high mechanical strength, chemical stability, aspect ratio, and field enhancement factor (β) are considered as ideal field emitters. In this thesis, coating of h-BN onto carbon nanotubes induces polarization at interfaces and charges become localized at N and C atoms respectively. Field emission of coated tubes is found to be highly stable and current density fluctuates within 4%. Study further reveals that electric field established between coatings and tubes facilitates charge transfer across interfaces and electrons are emitted through occupied and unoccupied bands of N and B atoms. Measurements give turn on field = 6.51 V/μm for CNTs and 2.65-2.67 V/μm for coated tubes; the threshold field being measured to be 9.82 V/μm and 4.41-4.43 V/μm respectively.

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