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Modeling Rotating Packed Bed on Absorption of CO2 by Aqueous Amines and Ammonia Solutions
Dissertation

Modeling Rotating Packed Bed on Absorption of CO2 by Aqueous Amines and Ammonia Solutions

KANG,JIA-LIN
Doctor of Philosophy (PHD), 國立清華大學, 化學工程學系所
2016

Abstract

二氧化碳捕獲 超重力旋轉床 醇胺溶液 氨水溶液 工業級設計 CO2 capture rotating packed bed monoethanolamine solution dilute ammonia Industrial scale design
The contributions of this dissertation are listed as following: • Developed a model of the carbon dioxide absorption by monoethanolamine and dilute ammonia solutions in a rotating packed bed based on two-film theory. • Found out that temperature bulge can be found in the rotating packed bed when a large amount of carbon dioxide was removed. • Found out that use of a modified expression for the apparent kinetic constant in the enhancement factor is necessary to predict experiment results using high amine concentrations. • Compared to the traditional packed bed and rotating packed bed by models for different throughput rates, ranging from bench scale to industrial scale. • Found out that the apparent intensification effect of the rotating packed bed is more significant for ammonia than for monoethanolamine solution because of the different operating of CO2 loading. • Found out that the Height of a Transfer Unit is inappropriate to be an indicator for intensification effect of volume.

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