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Titanium Silicide Nanocrystallites and One-Dimension Ordered Ti-Silicide Arrays on SiGe Substrate
Dissertation

Titanium Silicide Nanocrystallites and One-Dimension Ordered Ti-Silicide Arrays on SiGe Substrate

Tzu-Hsien Yang
Doctor of Philosophy (PHD), 國立清華大學, 材料科學工程學系
2004

Abstract

鈦矽化物 奈米微晶 自我組裝 非晶質 矽鍺基材 Ti-silicide nanocrystallite self assemble amorphous Si Ge substrate
The first part includes: 1. Formation of Ti silicide nanocrystals in the amorphous interlayers in ultrahigh vacuum deposited Ti thin films on (001) Si, 2. Auto correlation function analysis of phase formation in the initial stage of interfacial reactions of multilayered titanium-silicon thin films, 3. Formation of titanium silicides in well-mixed multilayered Ti-Si thin films at room temperature. The second part is on self-assembled TiSi2 quantum dot arrays on relaxed epitaxial Si0.7Ge0.3 on (001)Si. The formation of the one-dimensional ordered structure is attributed to the nucleation of TiSi2 nanodots on the surface undulations induced by step bunching on the surface of SiGe film. The step bunching is owing to the miscut of the wafers from normal to the (001)Si direction.

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