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Effects of Channel Geometry on Two-Phase Flow Phenomena at the anode in a micro-DMFC--with CO2 Bubbles Produced by Chemical Reactions of H2SO4 and NaHCO3
Thesis

Effects of Channel Geometry on Two-Phase Flow Phenomena at the anode in a micro-DMFC--with CO2 Bubbles Produced by Chemical Reactions of H2SO4 and NaHCO3

Hsian-Huei Huang
Masters, 國立清華大學, 工程與系統科學系
2006

Abstract

直接甲醇燃料電池 雙相流 漸擴流道 DMFC two-phase flow diverging flow channel
The present study utilizes sulfuric acid (H2SO4) solution and sodium bicarbonate (NaHCO3) solution mixing in the minichannel to produce carbon dioxide (CO2) through chemical reactions to simulate the two-phase flow transportation at the anode side of a DMFC through the following chemical reaction. Research results shows that the upstream flow pattern in three kinds of flow channel (SSF, SDSF-2□, SDSF-3□) is mostly bubbly flow; the downstream flow pattern is mostly slug flow or annular flow. Few CO2 bubbles are generated in SDSF-2□□Under the condition of low concentration. This could be the fluid velocity in SDSF-2□□□is fast, causing poor mixing of two working solutions On the other hand, more CO2 bubbles are produced in SDSF-3□□due to slower fluid velocity, and the mixing of two working solutions is better. More CO2 bubbles are generated at U-bends. This could be when fluid flow through a U-bend, a secondary flow will take place there. The CO2 bubbles are generated in three kinds of flow channel growing approximately linearly. The experimental pressure drop part, the pressure drops in SDSF-3□ is lower than those of SSF and SDSF-2□□ All of the two-phase pressure drop data exhibit a small amplitude, high frequency oscillation of about 45Hz.

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