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Giant Thermoelectric Effect of Nano-Gaps and its Enhancement Methods
Thesis

Giant Thermoelectric Effect of Nano-Gaps and its Enhancement Methods

Ho, Guan-You
Masters, 國立清華大學, 動力機械工程學系
2011

Abstract

熱電效應 Seebeck 係數 奈米間隙 thermoelectric effect Seebeck coefficient nano-gap
Thermoelectric materials can be used for power generation and heating or cooling applications. The figure of merit (ZT) of thermoelectric materials, which determines their efficiency in a thermoelectric device, remains low for most bulk materials. Nanoscale and nanostructured thermoelectric materials are promising for increasing ZT relative to the bulk. Based on the characters of thermoelectric materials, we need a material or structure with low thermal conductivity and high electrical conductivity to enhance the ZT. Therefore, we provide a new idea. In our structure, we can even neglect the thermal conductivity of phonons with discontinuous structure. Besides, we add different materials into the gap in order to improve the thermoelectric effect. We show that the Seebeck coefficient can be higher with narrower gap. Besides, we add nano particles into the gap and it is found that the Seebeck voltage can increase over 10 times than that without nano particle in the gap. Different from other researches, the Seebeck coefficient we measured can reach the order of mV/K so we call it “Giant thermoelectric effect.”

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