Logo image
PET/SiO2奈米複合材料 之結構與結晶行為研究
Thesis

PET/SiO2奈米複合材料 之結構與結晶行為研究

辛柏寰
Masters, 國立清華大學, 化學工程學系
2015

Abstract

小角度X光散射 結晶動力學 SAXS crystallization behavior
Polyethylene terephthalate (PET) is a very wildly used polymer material. Generally speaking, it is consumed by food package and clothing fiber industry. In order to improve its economic value, some scientists try to produce optical grade PET film. This kind of optical film will be used as back sheet of flexible touch panel. Due to the physical property of PET film, it will accumulate electrostatic and therefore make it hard for further processing. Adding SiO2 nanoparticle in PET film can reduce electrostatic; however, the particle size and its dispersity will contribute to haze, some kind of negative effect on optical film. We attempt to understand the interaction between SiO2 nanoparticle and PET by small angle X-ray scattering (SAXS), wide angle X-ray scattering (WAXS), differential scanning calorimetry (DSC), and transmission electron microscope (TEM). After several experiments, we discover that at low amounts of SiO2 nanoparticle (~1wt%) will increase the crystallization rate of PET. On the other hand, the larger concentration of SiO2 nanoparticle (~5wt%) the crystallization rate of PET will be suppressed. Furthermore, the SiO2 will disperse in PET in a fractal structure, the change of temperature will not change its structure.

Metrics

1 Record Views

Details

Logo image