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三維瀝青基碳碳複合材料應用於超高溫氣冷式反應器(VHTR)爐心環境之微結構變化
Thesis

三維瀝青基碳碳複合材料應用於超高溫氣冷式反應器(VHTR)爐心環境之微結構變化

任漢亞
Masters, 國立清華大學, 工程與系統科學系
2010

Abstract

碳碳複合材料 輻射損傷 石墨化程度 平面間距(d002) dpa HRTEM carbon-carbon composite materials radiation damage evolution of microstructures
Carbon-carbon composites are deemed as candidate materials for applications in very high temperature reactors (VHTRs). In a VHTR, carbon-carbon composite materials would experience severe environmental impacts of both a high radiation fluence (about 1.7~12.2×1020 neutron/cm2 per year)[87] and high temperatures (~1200 oC), and radiation damage is accordingly expected. In this study, samples prepared from a three-dimensional pitch-based carbon-carbon composite material were irradiated with a 4 MeV C2+ ion beam emitted by an accelerator to deliberately induce various levels of radiation damage on the samples at 1000 oC. Transmission electron microscopy analyses were then conducted to examine the evolution of microstructures in the samples, and a scanning electron microscope was used to examine the changes in surface morphology. It was found that an accumulated fluence of 8.0*1021 /m2 at 1000 oC resulted in cracks between the matrix and the fiber in the sample. These interfacial cracks were all parallel to the fiber orientation. The fiber/matrix bonding strength might play an important role in the mechanical property of the carbon-carbon composite material. In the meantime, cracks were also found at the fiber side of the sample irradiated under the same condition.

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