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二價銅、二價鎳巨環錯合物配位化學之研究與化學教育
Thesis

二價銅、二價鎳巨環錯合物配位化學之研究與化學教育

王柏森
Masters, National Tsing Hua University
2003

Abstract

四胺基大環配位子x光晶體繞射金屬錯合物晶體結構著作化學 macrocyclic ligandX-ray diffractionmetal complexescrystal structurearticleChemistry
Abstract Two macrocyclic ligands, 1,4,7,11-Tetraazacyclotetradecane and 3-[8-(2-Cyano-ethyl)-3,5,7,7,10,12,14,14-octamethyl-1,4,8,11tetraaza-cyclotetradec-1-yl]-propionitrile,two macrocyclic transition metal complexes, cis-Diaqua(1,4,7,11-Tetraazacyclotetradecane) nickel(II) Chorideand {3-[8-(2-Cyano-ethyl)-3,5,7,7,10,12,14,14-octamethyl-1,4,8,11tetraaza-cyclotetradec-1-yl] -propionitrile-N,N,N,N,}corpper(II) Choride, have been prepared. The crystal structures of these two complexes have been determined by X-ray diffraction. Three articles were finished in these two years:1. Chen Hao Chen Mei Ling Cheng Po Sen Wang Cho Ying Lu Yi Hsuan Li Cheng Shao Cheng Te Ming Chiang Meng Yun Chen Hsin Ying Peng Pin Chien Huang Chung-Sun Chung”Applying an Experimental Method of Instruction to Enhance Senior High School Student,Creativites in Chemistry.” Chemistry, 2003, 61, pp.551-560.2. Sheng Kang Chang Po Sen Wang Cho Ying Lu Yi Hsuan LiTe Ming Chiang Meng Yun Chen Hsin Ying Peng Pin Chien HuangChung-Sun Chung “Applying Champagne and Bunce,s Learning-theory Based Science Teaching Method To Enhance Senior High School Students, Creativities in Chemistry :Millikan oil-drop experiment.”3. Yung-Jan Lin, Po-Son Wang, Tarun Kumar Misra, Chung-Sun Chung “Kinetic studies of the conversion of to the square planar complex。”

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