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二硫化鉬之化學修飾
Thesis

二硫化鉬之化學修飾

劉威伸
Masters, 國立清華大學, 材料科學工程學系
2015

Abstract

二硫化鉬 化學修飾 羅丹明B 二甲基甲醯胺 P型 N型 Molybdenum disulfide functionalization Rhodamine B Dimethylformamide p doping n doping
Our research dedicate to chemical functionalization and effect of Raman and PL that molecular induce, we conclude mechanism of rhodamine B and dimethylformamide, by chemical functionalization, electrons can transfer to molybdenum disulfide and change its optical and electric properties. We confirm that molecular cause molybdenum disulfide what effect is induced by Raman and Photoluminescence, observe distribution and uniformity of molecular by AFM. Finally, we measure device that are made of molybdenum disulfide and show that molecular functionalization change electrical properties of molybdenum disulfide indeed. According to results of Raman and PL, we can discern what effect molecular cause and conclude mechanism of molecular. Our research shows rhodamine B that has benzene and electron-withdrawing can cause molybdenum disulfide p-doping, however, dimethylformamide contains electron-donating and causes molybdenum disulfide n-doping. Our research offers results of chemical functionalization that we can refer to change electrical properties of molybdenum disulfide in future.

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