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以3w法量測Bi0.5Sb1.5Te3薄膜之熱傳導係數
Thesis

以3w法量測Bi0.5Sb1.5Te3薄膜之熱傳導係數

王昱筑
Masters, 國立清華大學, 材料科學工程學系
2007

Abstract

熱電材料 薄膜 Bi0.5Sb1.5Te3 熱傳導係數 3-omega method 晶粒尺寸 thermoelectrics thin films Bi0.5Sb1.5Te3 thermal conductivity 3-omega method grain size
Bi0.5Sb1.5Te3 thin films are deposited on silicon dioxide substrates by RF sputtering. By changing the substrate temperature, we acquire Bi0.5Sb1.5Te3 thin films with different grain size. The thermal conductivity of Bi0.5Sb1.5Te3 thin films is measured using the 3ω method, and the lattice thermal conductivity and the electrical thermal conductivity are separated using the Wiedemann-Franz law. The lattice thermal conductivity dominates because of the high resistivity of the Bi0.5Sb1.5Te3 thin films, and it increases with greater grain size. After annealing, the electrical thermal conductivity substantially increases because of the decreasing of the resistivity, and we conjecture that the increasing of the lattice thermal conductivity results from the decreasing of the defects number in grains due to the same grain size before and after annealing.

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