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以蛋白質序列、結構及固有動態來正確地預測酵素催化位點
Thesis

以蛋白質序列、結構及固有動態來正確地預測酵素催化位點

張燕華
Masters, 國立清華大學, 生物資訊與結構生物研究所
2013

Abstract

酵素 活性位點預測 序列 結構 固有動態 保留性分數 相對溶劑可接觸表面積 酸解離常數 空間叢集化分數 多元回歸 催化位點 enzyme active site prediction conservation intrinsic dynamics solvent accessibility acid dissociation constant spatial clustering score Gaussian Network Model GNM partial least squares regression PLS catalytic propensity catalytic site
The researches of active site predictions that are based on the analysis of sequence and structure are increasingly developing for the past few years. The scope of enzyme categories in prediction is no longer limited to some specific enzyme families. In this thesis, we provide a partial least squares regression model trained over 225 nonhomologous enzymes to predict the location of actives sites. We use conservation scores, catalytic propensity, intrinsic dynamics of enzymes, relative solvent accessibility(RSA), pKa changes, the average RSA deviation in sequential residues, distances between residues and domain center and the spatial clustering scores as prediction model inputs. The performance of our predictions is interpreted by sensitivity=0.35, specificity=0.54 and Matthews correlation coefficient(MCC)=0.38 when we select the top 2 candidates. Sensitivity=0.66, specificity=0.29 and MCC=0.38 when we select the top 7 candidates. The dominant features of residues of enzymes in PLS model are conservation, spatial clustering scores of prediction candidates, distance between residues and domain center and the average RSA deviation in sequential residues.

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