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使用硝酸表面改質與四乙氧基矽烷沉積之氧化矽對蜂窩狀表面結構之矽晶太陽電池表面鈍化的影響
Thesis

使用硝酸表面改質與四乙氧基矽烷沉積之氧化矽對蜂窩狀表面結構之矽晶太陽電池表面鈍化的影響

程仕豪
Masters, National Tsing Hua University
2010

Abstract

蜂巢結構結晶矽太陽電池硝酸改質四乙基氧化矽烷表面鈍化 honeycomb structurecrystalline solar cellNAOS treatmentTEOS oxidesurface passivation
In this thesis, we use the laser system and isotropic wet-etching to construct honeycomb structure on crystalline silicon solar cell and we also investigate the surface passivation effect of NAOS/TEOS application .First, we can find the positive fixed charge of NAOS /TEOS film and the film quality enhanced with annealing temperature from C-V & FTIR. The passivation effect can be verified by lifetime measurement. According to the former standard process flow, we find our cells have the problem of the very high series resistance. After we optimum the annealing parameter, we improve the F.F. from 0.13 to 0.71. Finally, we take the application of NAOS/TEOS passivation on crystalline silicon solar cell. The final parameter are:Mono: Jsc=34.28mA/cm2, Voc=0.57V, F.F.=0.72, η=14.06%Multi: Jsc=30.34 mA/cm2,Voc=0.52V, F.F.=0.66, η=10.41%

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