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利用金屬輔助化學蝕刻粗化方式製作多晶太陽能電池
Thesis

利用金屬輔助化學蝕刻粗化方式製作多晶太陽能電池

李鴻慶
Masters, National Tsing Hua University
2011

Abstract

多晶矽太陽能電池表面粗化金屬輔助化學性蝕刻 multicrystalline siliconsolar cellsurface texturingmetal assisted etching
In this thesis, the surface texturing for multicrystalline silicon by using metal-assisted chemical etching (MAE) method was carried out to fabricate solar cell. There were two kinds of etchant used in the MAE process. One was a mixture of HF, H2O2 and H2O and the other was a mixture of HF, Fe(NO3)3 and H2O. The metal used in the MAE process was Ag. The textured surface morphologies were analyzed by SEM and reflectance measurement. The different morphologies including bowl, cone and grating with high aspect ratio were fabricated. The average reflectance of textured surface is below 10% and the lowest reflectance is about 2~3% in the range of 400~600 nm. The efficiency of solar cell fabricated with HF/Fe(NO3)3/H2O is 8.24% and fabricated with HF/H2O2/H2O is 11.81%.

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