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可撓式高效率反相有機太陽能電池製程研究
Thesis

可撓式高效率反相有機太陽能電池製程研究

翁瑋澤
Masters, 國立清華大學, 電子工程研究所
2008

Abstract

軟性基板 反結構 碳酸銫 氧化鋅 三氧化鉬 原子層沉積 flexible substrate inverted solar cell Cs2CO3 ZnO atomic layer deposition
Recently, inverted organic solar cells have been widely investigated since their life time is much longer than those of conventional ones. In this research, we prepared two different materials as electron transport layer and employed different fabrication methods to manufacture the inverted organic solar cell on flexible substrate. In this work, an inverted organic solar cell based on P3HT:PCBM were spin-coated on two different electron transport layers which are cesium carbonate (Cs2CO3) and zinc oxide (ZnO) thin films. With these oxides, they changed the work function of ITO and metal electrode by forming a thin dipole layer. In Cs2CO3 experiment series, we promoted the device performance and stability by reducing the annealing temperature and the spin rate of the Cs2CO3 layers. As a result, the power conversion efficiency (PCE) of the devices improved to 2.2%. In our main study, we changed the film thickness of ZnO. The devices exhibit a PCE of 3.78% with optimum film thickness. As deposition temperature of ZnO thin film increases from room temperature to 80oC, the PCE increases from 3.78% to 4.18%, which is the highest performance for polymer solar cell on flexible substrates.

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