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各種因素對反應器壓力槽低合金鋼在沸水式反應器條件下環境促進破裂之裂縫成長速率的影響研究
Thesis

各種因素對反應器壓力槽低合金鋼在沸水式反應器條件下環境促進破裂之裂縫成長速率的影響研究

陳彥羽
Masters, National Tsing Hua University
2005

Abstract

裂縫成長速率輕水式反應器環境促進破裂腐蝕疲勞應力腐蝕破裂反應器壓力槽低合金鋼沸水式反應器應力強度因子範圍週期性部分卸除負荷溶氫電化學電位正常水化學加氫水化學 crack growth ratelight water reactorenvironmentally assisted crackingcorrosion fatiguestress corrosion crackingreactor pressure vessellow-alloy steelboiling water reactorstress intensity factor rangeperiodic partial unloadingdissolved hydrogenelectrochemical potentialnormal water chemistryhydrogen water chemistry
Crack growth rate (CGR) measurement is an important tool to understand the behaviors of the environmentally assisted cracking (EAC) of various materials used in light water reactor (LWR) environments. In addition, such measurements are also used to produce quantitative data on corrosion fatigue (CF) and stress corrosion cracking (SCC). This type of data is essential for structural integrity analyses, as well as for the lifetime estimation and reliability of existing or postulated defects.In this paper, behaviors of CF and SCC experiments with two different nuclear grade reactor pressure vessel (RPV) low-alloy steels (LAS) with low- (A508 Cl.2, 0.008 wt.%) or high-sulfur (A533B Cl.1, 0.018 wt.%) steel content at 288°C under simulated boiling water reactor (BWR) conditions are presented. CGR of RPV LAS was found to be dependent upon various mechanical factors such as the stress intensity factor range (?K), loading frequency (ν), rise time (ΔtR), and hold time (ΔtH) at maximum load. In CF tests, it was observed that the CGR increased as ?K increased under the same water quality and loading conditions. If ?K was similar, the higher the ν (or the shorter ΔtR), the higher was the CGR. In SCC tests, the longer the ΔtH, the slower the CGR was under periodic partial unloading (PPU) conditions.On the other hand, it was found that dissolved hydrogen (DH), which lowered the electrochemical potential (ECP), could effectively suppress the CGR in either CF or SCC tests. The mechanism of the suppressive effect of DH on the CGR and the water chemistry conditions near the crack tip was also discussed in this paper. And, effect of steel sulfur content on CGR was less pronounced under low-frequency loading (e.g., ν ? 4×10-3 Hz) and low-flow, oxidizing (e.g., ECP = 100-200mVSHE) BWR/normal water chemistry (NWC) conditions.After mean crack lengths of various test specimens were evaluated using a specific electrochemical oxide removal method (ENDOX treatment), many CGR data from this study were observed to be comparable with those obtained from some well-known CGR prediction models for BWR environments except in the hydrogen water chemistry (HWC) condition. However, the current CF CGR data with a low loading frequency (ν = 4×10-4 Hz) were not bounded by the model developed by Eason. Additionally, most of our SCC CGR data cannot be encompassed by the MPA Stuttgart models.

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