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含銅鐵鉑奈米顆粒之合成及結構之研究
Thesis

含銅鐵鉑奈米顆粒之合成及結構之研究

杜德洪
Masters, 國立清華大學, 工程與系統科學系
2003

Abstract

鐵鉑 磁性 奈米顆粒 自組裝 同步輻射 FePt iron platinm nanoparticle self-assembly magnetic synchrotron radiation
Fe Cu Pt nanoparticles were prepared by the simultaneous polyol reduction of platinum acetylacetonate and copper acetylacetonate and the thermal decomposition of iron carbonyl. The addition of copper promoted the disorder FCC structure to order structure, thereby reducing the temperature required for this transition about 50-100 . Under 500 annealing temperature and the same annealing condition, the coercivity of the Fe Cu Pt nanoparticles containing 11% copper was 243 Oe while the pure FePt nanoparticles were superparamagnetic. From the x-ray powder diffraction and x-ray absorption spectroscopy results, it was found that FePtCu ternary alloy was formed and the Fe site was replaced by Cu.

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