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奈米碳管-鐵氧磁體-碳基鐵粉/矽氧樹脂複合材料之電磁波屏蔽與吸收研究
Thesis

奈米碳管-鐵氧磁體-碳基鐵粉/矽氧樹脂複合材料之電磁波屏蔽與吸收研究

洪銘遠
Masters, 國立清華大學, 材料科學工程學系
2011

Abstract

電磁波屏蔽 碳基鐵粉 鐵氧磁體 electromagnetic shielding carbonyl iron powder ferrite
In this work, MWCNT-ferrite-CIP /silicone composites were fabricated. The electromagnetic shielding and absorption properties were measured by a network analyzer and calculated in 45 MHz ~ 4.5 GHz. The reflection loss was simulated from the obtained complex permeability and permittivity at various sample thicknesses. Electromagnetic shielding effectiveness was improved significantly with increasing MWCNT content over the percolation threshold of about 4 wt% when high electric conductivity resulted from well inter-connection among MWCNTs in the silicone matrix. Less than 5 % electromagnetic wave energy can be transmitted in 45 MHz ~ 4.5 GHz with the addition of 9 wt% MWCNT content. CIP /MWCNT composites generally show better absorption performances (reach 63.61% at 4.5 GHz) than others. With more MWCNTs, the capability of the high absorption is extended to lower frequency range. Ferrite/ MWCNT composites show better absorption performances than that would expect by simple addition. This surplus beneficial effect is proposed to be a result of that the electromagnetic wave got reflected back and forth by the fillers in the material and thus increased the probability of absorption. In some frequency ranges, the absorption of ferrite/ CIP/ MWCNT/ silicone composites is better than both ferrite only and CIP only composite. The reflection loss exceeding -20 dB was observed easily in 0.9 GHz ~ > 4.5 GHz with composite thickness from 3 mm to 10 mm. For 70 wt% CIP/ 5 wt% MWCNT/ silicone composite with 5 mm thickness, the reflection loss reached -91.2dB (99.9999999 %) at 2.28 GH and the bandwidth below -20 dB is 0.96 GHz. In addition, the highest useful frequency bands were observed for ferrite/ MWCNT/ silicone composites and the broadest -20dB bandwidth is observed for ferrite/ CIP/ MWCNT/ silicone composites.

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