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導電共軛高分子摻雜三重態激發子之能量傳輸研究
Thesis

導電共軛高分子摻雜三重態激發子之能量傳輸研究

陳鎧
Masters, 國立清華大學, 電子工程研究所
2004

Abstract

共軛高分子 三重態激發子 能量傳輸 conjugated polymer triplet emitter Energy transfer
This thesis studies on energy transfer process in conjugated polymer PFO doped with phosphorescent emitter (Btp)2Ir. By comparing photo-luminance (PL) spectrum and photo-induced absorption (PA) signal of polymer films with various doping concentration, we investigate the change in the population ratios and life time of singlet and triplet exciton of PFO. From the quenching of singlet exciton of PFO and reduced life time of triplet exciton of PFO, it concluded that both Forster energy transfer and Dexter energy transfer happen. However, high doping concentration cannot quench exciton of PFO completely and it may be due to the fact that (Btp)2Ir cannot disperse uniformly in PFO film.

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