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探討不同製程之碳化矽複合材料於高溫離子輻照環境下之空孔形成
Thesis

探討不同製程之碳化矽複合材料於高溫離子輻照環境下之空孔形成

邱奕哲
Masters, 國立清華大學, 工程與系統科學系
2012

Abstract

碳化矽複合材料 離子輻照 空孔 SiC composites ion irradiation void
Silicon carbide composites are considered as the plasma facing material in fusion reactors. Therefore, high dose neutron irradiation and helium accumulation due to emission of alpha-particles from (n,α) nuclear reaction in fusion reactor are significant issues in mechanical property. This thesis will focus on the effect of ion irradiation on void formation in different processed SiC/SiCf composites under high temperature environments. In this study, The novel SiC composite – SA-Tyrannohex SiC fiber-bonded composite was irradiated by 5.1 MeV-Si2+ and 300 keV-He+ at 1300℃ to 1500℃, respectively. The dose was up to 150 dpa and the helium accumulation concentration was 15000 appm. The microstructure evolution of irradiated SiC was examined by transmission electron microscopy. The average diameter of cavities induced by Si2+ irradiation increased both with the increasing temperature and irradiation damage, up to 2.5 nm at 150 dpa/1500℃. However, the number density of cavity was almost saturated at 50 dpa. No helium bubble was abserved in the 15000 appm irradiated sample at 1300℃ and 1500℃. Comparison to Hi-Nicalon Type-S compsite、Tyranno-SA composite and CVD polycrystalline SiC, SA-Tyrannohex fiber-bonded composite appears to has excellent resistance to cavity formation due to small grain size during Si2+ and He+ irradiation at high temperatures.

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