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有機溶劑在聚甲基丙基酸甲酯裡引發裂紋與裂紋癒合之行為研究
Thesis

有機溶劑在聚甲基丙基酸甲酯裡引發裂紋與裂紋癒合之行為研究

Wu, Hsien-Chun
Masters, 國立清華大學, 材料科學工程學系
2008

Abstract

裂縫 2-乙基己醇 甲醇 溶劑引發應力 聚甲基丙基酸甲酯 crack 2-ethylhexyl alcohol methanol solvent-induced stress PMMA
Diffusion in polymer and solvent-induced stresses has been well investigated in the past. In this experiment, we found that 2-ethylhexyl alcohol could rapidly extract methanol from PMMA by mass measurement, thickness measurement and FTIR spectrum. Crack formed during methanol desorption. We observed the crack growth with optical microscope (OM) and studied different parameters affected crack growth like immersion tempersture and immersion time. Different immersion times and immertion temperatures carried out different crack densities and crack depths. We utilized tensile test to quantify the extent of crack destruction on specimens and the software ImageJ to calculate the crack density and crack depth. Crack healing in PMMA with solvent has been proposed. We heals the cracked specimen with methanl at different temperatures and utilized tensile test to quantify the extent of crack healing. The healing rate increases with increasing temperature. Finally. we used mixture of methanol with dye to heal the cracked specimen which is possiblely applied for embedding particles in polymer.

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