Abstract
本實驗擬選擇BTDA（3,3'-4,4'-benzophenone tetracarboxylic dianhydride）和6FDA（4,4'-Hexafluoroisopropylidene-bis-phthalic anhydride）雙酸酐單體及BAMP（bis(3-aminophenyl)methylphosphine oxide）和MDA（4,4-diaminodiphenyl methane）雙胺單體，並以NA（ Nadic anhydride）為尾罩基（End Capped）合成可溶性加成型聚醯亞胺 黏著劑，探討其耐熱性、耐燃性、剪切強度及剝離強度等機械性質和物性 。並加入橡膠（Rubber）摻混（Blending），探討其對黏著性質之影響。 Addition polyimide oligomers have been synthesized from 3,3'-4,4'-benzophenone tetracarboxylic dianhydride，4,4'- hexafluoroisopropylidene-bis-phthalic anhydride，bis(3- aminophenyl)methylphosphine oxide and 4,4-diaminodiphenyl methane using nadic anhydride as end-caps.The addition polyimide prepolymers were characterized for solubility and thermal stability on heating in air and N2 .Adhesive strengths of polyimides were obtained at ambient ，200℃and 300℃ temperatures. Also a series of studies evaluating theeffects of added elastomers on the adhesive strengths of a high-temperature addition polyimide adhesive is reviewed.