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金金屬催化炔醯胺與丙烯醇和丙炔醇進行多種不同加成反應以及環化反應和鋅金屬催化炔醯胺與Chloramine-T進行氯胺化反應
Thesis

金金屬催化炔醯胺與丙烯醇和丙炔醇進行多種不同加成反應以及環化反應和鋅金屬催化炔醯胺與Chloramine-T進行氯胺化反應

林立軒
Masters, 國立清華大學, 化學系
2015

Abstract

金金屬催化 鋅金屬催化 克萊森反應 1,4加成反應 多氯亞胺
Chapter 1 We developed the gold-catalyzed reaction with allylic alcohol and propargyl alcohol delivering variety of product such as Claisen rearrangement’s type product, 1,4 addition’s type product and undergo cyclization followed by 1,4 addition’s type product. Chapter 2 An efficient Zinc catalysis enhances the reactivity of the Chloramine-T, and Chloramine-T react with the ynamides which has the vibration’s olefin. The reaction will undergo the chloroamination of ynamides with Chloramine-T at room temperature. The reaction will get the Polyhalogenaldimes in the moderate to good yields. The products will include one primary C-Cl bond and one secondary C-Cl bond, with these good leaving group, it can promote their interaction with divergent nucleophiles to form numerous novel compounds.

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