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雙相磷酸鈣骨填充材料與其生物效應評估
Thesis

雙相磷酸鈣骨填充材料與其生物效應評估

黃國昌
Masters, National Tsing Hua University
2004

Abstract

氫氧基磷灰石雙相三鈣磷酸鹽多孔
Hydroxyapatite(HA) has been wildly studied and used in bony implant, because HA has the advantages, such as free of cell toxicity, excellent bio-compatibility, and it is the major component of human bone. Beta-tricalcium phosphate(β-TCP) is also popular in implantation usage, due to its ability to release abundant calcium and phosphate ions that will provoke the bony growth. In this study, I aimed to prepare porous biphasic calcium phosphate materials as bony implant. We used a single phase HA and a foaming agent to form a porous biphasic(HA and β-TCP) material after one step calcination.The major foaming agent used is sucrose. HA and sucrose with the ratio 1 to 0.75 was found optimal. After being calcined at 1000℃ for 30min, a porous and biphasic material was obtained. The sucrose decomposed and evaporated during the process. The material has micro- and macro-pores, and the pore size ranges from 0~50 μm and 100~150 μm, respectively. The porosity was higher than 70%, HA could be higher than 60wt%, and the compressive strength was about 0.2~0.6 MPa. All these parameters could be adjustable by HA/sucrose ratio and calcination parameters. The synthesized material was free of cell toxicity, and there was no long-term inflammation in situ.

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