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電化學法多巴胺定量感測之氮參雜超奈米微晶鑽石電極與CMOS感測電路
Thesis

電化學法多巴胺定量感測之氮參雜超奈米微晶鑽石電極與CMOS感測電路

吳宗龍
Masters, 國立清華大學, 電子工程研究所
2010

Abstract

超奈米微晶鑽石 多巴胺 帕金森氏症 阿茲海默症 電化學氧化還原反應 交叉電極感測器 CMOS 感測電路 微機電技術 UNCD Dopamine Parkinson's Disease Alzheimer's Disease Electrochemical Oxidation Reduction Reaction IDA Electrodes CMOS MEMS
In this study, high sensitivity UNCD (ultrananocrystalline diamond) micrielectrodes for real-time dopamine detection are investigated. It is believed that such a device could be used in the future for monitoring the change of dopamine concentration in Parkinson's disease and Alzheimer's Disease patients. High Pressure Liquid Chromatography (HPLC) has been widely used in hospitals due to its high sensitivity; however the expensive cost makes it inconvenient for general users. In order to improve this problem, a new dopamine sensor based on electrochemical detection is proposed. The dopamine sensor in this thesis includes N-doped UNCD interdigitated microelectrodes and CMOS (Complementary Metal Oxide Semiconductor) sensing circuit. First of all, by employing MEMS (Micro-Electro-Mechanical Systems) technology the sensor is fabricated on the silicon substrate coated with Si3N4. As the dopamine is detected by microelectrode, the sensor generates a current signal resulted from oxidation and reduction. Then, this current signal is converted to a voltage signal by the sensing circuit. Finally, the dopamine concentration can be calculated from the output data. Since the UNCD has flat surface, superior physical and chemical properties, it’s an excellent candidate material for microelectromechanical (MEMS) application. Its conductivity is close to that of an the insulator, so it has limited applications. By doping some elements to improve its conductivity, it can help the UNCD on the semiconductor and biomedical device applications.

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