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高密度電漿化學氣相沈積法成長含氧碳化矽做為氫離子感應膜之研究
Thesis

高密度電漿化學氣相沈積法成長含氧碳化矽做為氫離子感應膜之研究

林嘉柏
Masters, National Tsing Hua University
2003

Abstract

高密度電漿離子感應場效電晶體含氧碳化矽酸鹼感測器三甲基矽烷 HDPCVDISFETSiOxCypH meter3MS
AbstractThe ion sensitive field effect transistor (ISFET) is a microsensor consists of the theorem of electrochemistry and the characteristic of a field effect transistor. The principle of the MOSFET is be used for ISFET. The metalline gate of the MOSFET is substituted for reference electrode / electrolyte / insulator. Hence, ISFET is a device composed of a ion selective electrode and a MOSFET device.In this thesis the silicon oxycarbide ( SiOxCy ) membrane has been prepared by high density plasma chemical vapor deposition, HDPCVD, method as a novel pH-sensitive layer under different gas flow rate (3MS/O2) and plasma power at different temperatures. The SiOxCy membrane was directly deposited on the p-type silicon substrate by HDPCVD to form the SiOxCy / Si EIS structure. The variations of flat band voltage were reported by C-V measurement to survey the sensitivity of membrane. The characteristics of membrane were measured and analysed by Electron spectroscopy for chemical analysis (ESCA), Energy dispersive spectrometer (EDS), n&k, Fourier transform IR (FTIR), Grazing incident X-ray diffraction and Atomic force microscopy (AFM), respectively.Experimental results show that the fabrication parameters and characteristics of SiOxCy membrane are determined at gas flow rate 20/2 (3MS/O2), the plasma power 600W at 200oC via the EIS structure. There exhibits the best pH response of about 56.35 mV/pH in the range of pH 1-11. The pH response increases to 64.35 mV/pH via the double layers of the EIS structure.

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