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金屬改質TiSBA-15複合材料的合成、鑑定與光降解研究
Thesis

金屬改質TiSBA-15複合材料的合成、鑑定與光降解研究

Ou, Hong-De
Masters, 國立清華大學, 生醫工程與環境科學系
2008

Abstract

Ti改質SBA-15 金屬改質 光催化 輻射敏感 Ti-containing SBA-15 metal modification Photocatalysts Radiosensitive
Abstract Highly ordered titanium-containing SBA-15(TiSBA-15) materials have been successfully synthesized through co-precipitation synthesis. In order to increase the photocatalytic efficiency and optical usage range of TiSBA-15, modified composites are made by doping with rare-earth metal cerium (Ce) and noble metal platinum (Pt) through photodeposition method respectively. The prepared materials were characterized by ICP-MS, BET, SEM/EDX, TEM and XRD. Their catalytic performances were evaluated for degradation of methylene blue (MB) by UV light and Gamma-ray in a liquid phase. It was observed that the properties of morphology, crystalline structure, and photocatalytic performance would be influenced with various titanium contents. The photocatalytic activity increases with an increasing Ti content. In addition, for modified TiSBA-15 materials with Pt and Ce, the photocatalytic performance of Pt/TiSBA-15 series is better but Ce/TiSBA-15 series is worse than that of unmodified ones by UV light. Nevertheless, we find that the prepared Ce/TiSBA-15 can be activated under Gamma-ray irradiation to photocatalytically decompose the MB.

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