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A comparative study on sorption and diffusion of Cs in crushed argillite and granite investigated in batch and through-diffusion experiment
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A comparative study on sorption and diffusion of Cs in crushed argillite and granite investigated in batch and through-diffusion experiment

Chuan-Pin Lee, Shih-Chin Tsai, Ming-Chee Wu, Tsuey-Lin Tsai, Yu-Lin Tu 和 Ling-Jen Kang
Journal of radioanalytical and nuclear chemistry, 卷.311(2), 頁碼.1155-1162
01/02/2017
Web of Science ID: WOS:000394343200024

摘要

Article Chemistry Chemistry and Materials Science Diagnostic Radiology Hadrons Heavy Ions Inorganic Chemistry Nuclear Chemistry Nuclear Physics Physical Chemistry
The batch and through-diffusion experiments in this study were conducted and compared in order to investigate the sorption and diffusion of cesium (Cs) for two potential host rocks in Taiwan: argillite from Taitung and granite from Kinmen Island, with the purpose of establishing a reliable safety-performance assessment methodology for the final disposal of low level radioactive waste. The results of Cs mapping by scanning electron microscope equipping by energy dispersive spectrometer (SEM–EDS) showed that the distribution of Cs on argillite and granite were enriched in illite and biotite, respectively. In addition, it showed that higher sorption capacities were found for argillite than granite; due to the clay mineral content (illite) in the argillite. Experiments for diffusion of Cs is agreement to the values estimated for the diffusive results ( D a ) of Cs in argillite were revealed to be lower than those of granite.

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