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A facile synthesis of phytosphingosine from diisopropylidene-D-mannofuranose
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A facile synthesis of phytosphingosine from diisopropylidene-D-mannofuranose

Hsin-Yi Chiu, Der-Lii M. Tzou, Laxmikant Narhari PatkarChun-Cheng Lin
Journal of Organic Chemistry, 卷.68(14), 頁碼.5788-5791
07/2003
PMID: 12839486

摘要

Organic Chemistry
In the present study, an efficient method with a high overall yield for preparing phytosphingosine and an analogue was developed. Starting with commercially available 2,3;5,6-di-O-isopropylidene-D-mannofuranose, a variety of lipid moieties were incorporated to obtain phytosphingosine and an analogue. Through an eight-step manipulation, phytosphingosine was obtained with an overall yield of 57%.

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