摘要
Potassium-pre-intercalated δ-phase MnO 2 is uniformly grown on carbon nanofibers for the positive electrode of asymmetric supercapacitors. An electrospun CNF is chemically activated with KOH at 800 °C for the negative electrode, showing ideal capacitive behavior. The crystallinity of MnO 2 is significantly reduced by the pre-intercalation of K ions into its layered structure. This textural characteristic is beneficial to the K + diffusion into/out the interlayer structure, leading to effective utilization of the electroactive material of K x MnO 2 . This unique composite electrode provides both ideal pseudo-capacitive behavior from K x MnO 2 and excellent electric conductivity from the CNF network, exhibiting a fairly high specific capacitance value of 279 F g -1 at 1 A g −1 with ca. 82.3% capacitance retention from 1 to 32 A g −1 . A flexible ASC consisting of the positive K x MnO 2 @CNF electrode, a paper separator, and the negative ACNF electrode is successfully assembled. This cell shows superior ASC performances: a high cell voltage between 0 and 2 V, excellent capacitance retention (10,000 cycles with 10% decay), and simultaneously reaching high specific energy and power of 21.1 Wh kg −1 and 9.5 kW kg −1 . The charge storage behavior of this cell without bending and with a bending angle of 90° shows no apparent difference, demonstrating its potential in the next-generation flexible energy storage devices.