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A novel interpenetrating diamondoid network from self-assembly of N,N′-di(4-pyridyl)adipoamide and copper sulfate: An unusual 12-fold, [6 + 6] mode
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A novel interpenetrating diamondoid network from self-assembly of N,N′-di(4-pyridyl)adipoamide and copper sulfate: An unusual 12-fold, [6 + 6] mode

Yi-Fen Hsu, Chia-Her Lin, Jhy-Der Chen 和 Ju-Chun Wang
Crystal Growth and Design, 卷.8(4), 頁碼.1094-1096
04/2008
DOI: https://doi.org/10.1021/cg701209k

摘要

Chemistry (all) Materials Science (all) Condensed Matter Physics
The polymeric complex [CuSO 4 (L)(H 2 O) 2 ]∞ 1, which was prepared by the reaction of a flexible ligand N,N'-di(4-pyridyl)adipoamide), L, and copper sulfate forms a 12-fold diamondoid network showing an unusual [6 + 6] mode of interpenetration. The L ligands in 1 adopt the AAA trans and GAG trans conformations which also differ in the dihedral angle between the two pyridyl rings. © 2008 American Chemical Society.

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