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A novel oxidative desulfonylation. Facile conversion of sulfones to aldehydes or ketones
Journal article   Peer reviewed

A novel oxidative desulfonylation. Facile conversion of sulfones to aldehydes or ketones

Jih Ru Hwu
Journal of Organic Chemistry, Vol.48(23), pp.4432-4433
1983

Abstract

Alkyl, allylic, benzylic, and cycloalkyl sulfones can be converted to aldehydes or ketones in good-to-excellent yields by treatment with n-BuLi followed by Me 3 SiOOSiMe 3 . Preparation of 18 O-labeled carbonyl compounds with Me 3 Si 18 O 18 OSiMe 3 was also successful. © 1983 American Chemical Society.

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