An electron-rich molybdenum-molybdenum quintuple bond spanned by one lithium atom

Shin-Cheng Liu; Wei-Lun Ke; Jen-Shiang K. Yu; Ting-Shen Kuo; Yi-Chou Tsai

doi:10.1002/anie.201200122

An electron-rich molybdenum-molybdenum quintuple bond spanned by one lithium atom

期刊文章

同儕審查

An electron-rich molybdenum-molybdenum quintuple bond spanned by one lithium atom

Shin-Cheng Liu, Wei-Lun Ke, Jen-Shiang K. Yu, Ting-Shen Kuo 和 Yi-Chou Tsai

Angewandte Chemie - International Edition, 卷.51(26), 頁碼.6394-6397

06/2012

DOI: https://doi.org/10.1002/anie.201200122

PMID: 22644667

摘要

amidinato ligands

bond theory

lithium

molybdenum

multiple bonds

Chemistry (all)

Catalysis

Take five: A unique quintuply bonded dimolybdenum complex [Mo ₂ (μ-Li){μ-HC(N-2,6-Et ₂ C ₆ H ₃ ) ₂ } ₃ ] (see picture) was synthesized and characterized. The Mo-Mo interaction includes an unexpected bridging Li ⁺ ion. Calculations indicate the bridging Li ⁺ ion does not perturb the Mo-Mo bond length (2.0612(4) Å), but results in a relatively small effective Mo-Mo bond order of 3.67. Copyright © 2012 WILEY-VCH Verlag GmbH & Co. KGaA, Weinheim.

指標

1 檢視次數

詳細資料

題名: An electron-rich molybdenum-molybdenum quintuple bond spanned by one lithium atom
翻譯題名: An electron-rich molybdenum-molybdenum quintuple bond spanned by one lithium atom
創作者：: Shin-Cheng Liu (作者) - Department of Chemistry , Frontier Research Center on Fundamental and Applied Sciences of Matters , National Tsing Hua University
Wei-Lun Ke (作者) - Department of Chemistry , Frontier Research Center on Fundamental and Applied Sciences of Matters , National Tsing Hua University
Jen-Shiang K. Yu (作者) - Institute of Bioinformatics and Systems Biology
Ting-Shen Kuo (作者) - National Taiwan Normal University
Yi-Chou Tsai (作者) - Department of Chemistry , Frontier Research Center on Fundamental and Applied Sciences of Matters , National Tsing Hua University
學術資源類型: 期刊文章
出版日期: 06/2012
出版資訊: Angewandte Chemie - International Edition, 卷.51(26), 頁碼.6394-6397
語言: 英語

An electron-rich molybdenum-molybdenum quintuple bond spanned by one lithium atom

摘要

相關連結

指標

詳細資料

National Tsing Hua University 社交媒體