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Assembly of a water-insoluble strontium metal-organic framework with luminescent properties
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Assembly of a water-insoluble strontium metal-organic framework with luminescent properties

Sheng-Han Lo, Hsin-Kuan Liu, Jun-Xiang Zhan, Wei-Cheng Lin, Ching-Che Kao, Chia-Her LinVítězslav Zima
Inorganic Chemistry Communications, 卷.14(10), 頁碼.1602-1605
10/2011

摘要

Luminescent Metal-organic framework Strontium complex Water-insoluble Physical and Theoretical Chemistry Inorganic Chemistry Materials Chemistry
A new strontium metal-organic framework, [Sr 2 (BTEC)(H 2 O) 4 ]2H 2 O (1) (H 4 BTEC = benzene-1,2,4,5-tetracarboxylic acid), has been successfully synthesized by mixing the starting reagents. The single-crystal structure analysis showed that compound 1 displayed three-dimensional structures containing inorganic motifs with two-dimensional layers pillar-connected through organic linkers and forming water-coordinated neutral framework. Further studies revealed that compound 1 was insoluble in water and that it emitted strong luminescence at approximately 437 nm after dehydration. © 2011 Elsevier B.V. All rights reserved.

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