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(Benzonitrile-kN)chlorido[hydrido-tris(pyrazol-1-yl-kN2)borato] (triphenyl-phosphine-kP)ruthenium(II) ethanol solvate
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(Benzonitrile-kN)chlorido[hydrido-tris(pyrazol-1-yl-kN2)borato] (triphenyl-phosphine-kP)ruthenium(II) ethanol solvate

Hung-Chun Tong, Yu-Chen Hung, Po-Yo Wang, Chia-Her Lin 和 Yih-Hsing Lo
Acta Crystallographica Section E: Structure Reports Online, 卷.65(4)
2009
DOI: https://doi.org/10.1107/S1600536809010265

摘要

Chemistry (all) Materials Science (all) Condensed Matter Physics
The reaction of [Ru(C 9 H 10 BN 6 )Cl(C 18 H 15 P) 2 ] with benzo-nitrile leads to crystals of the title compound, [Ru(C 9 H 10 BN 6 )Cl(C 18 H 15 P)(C 7 H 5 N)]·C 2 H 5 OH. In the crystal structure, the environment about the ruthenium metal center corresponds to a slightly distorted octa-hedron with an average N - Ru - N bite angle of the Tp ligand of 86.6 (2)°. © 2009.

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