摘要
The self-assembly of polymeric micelles and colloidal dispersions into intricate structures represents a transformative approach in contrast to traditional fabrication methods for creating new functional materials. Despite remarkable advancements in the field, there exists substantial potential for further progress. In the past two decades, scientists have innovated and applied sophisticated methods for synthesizing nanocrystals of diverse geometries and polymeric materials with varying molecular characteristics. These synthetic pathways play a pivotal role in the facile fabrication of a multitude of nanostructures, which also greatly facilitates our understanding of the governing principles of meso and nano object self-assembly. This review focuses on the complex packing structures of block copolymer micelles and colloidal particles, with a particular emphasis on the Frank-Kasper phase. A comprehensive exploration of the recent theoretical and experimental advances in this interdisciplinary field is presented. By drawing parallels between the self-organized formation of both hard particles and soft micelles, this review aims to provide a fundamental understanding of the underlying physics and chemistry that contribute to the emergence of complex packing behavior. This knowledge is instrumental in the design and engineering of structures tailored to specific applications, fostering further innovation in the realm of nanomaterials.