Catalytic asymmetric allylation of aldehydes via a chiral indium(III) complex

Yong-Chua Teo; Kui-Thong Tan; Teck-Peng Loh

doi:10.1039/b412736f

Back

Catalytic asymmetric allylation of aldehydes via a chiral indium(III) complex

Journal article

Peer reviewed

Catalytic asymmetric allylation of aldehydes via a chiral indium(III) complex

Yong-Chua Teo, Kui-Thong Tan and Teck-Peng Loh

Chemical Communications, (10), pp.1318-1320

14/03/2005

DOI: https://doi.org/10.1039/b412736f

Abstract

A chiral indium complex has been discovered to effect high enantioselectivities in the addition of allyltributyl stannanes to aldehydes. The allylation of a variety of aromatic, α,β-unsaturated and aliphatic aldehydes resulted in good yields and high enantioselectivities (90-96% ee). © The Royal Society of Chemistry 2005.

Metrics

1 Record Views

Details

Title: Catalytic asymmetric allylation of aldehydes via a chiral indium(III) complex
Creators - without role: Yong-Chua Teo - Department of Chemistry , National University of Singapore
Kui-Thong Tan - Department of Chemistry , National University of Singapore
Teck-Peng Loh - Department of Chemistry , National University of Singapore
Publication Details: Chemical Communications, (10), pp.1318-1320
Identifiers: 9957769523806774
Academic Unit: Institute of Analytical and Environmental Sciences, College of Nuclear Science, National Tsing Hua University
Language: English
Resource Type: Journal article

Catalytic asymmetric allylation of aldehydes via a chiral indium(III) complex

Abstract

Related links

Metrics

Details

National Tsing Hua University Social media