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Chiral amplification in one-dimensional helical nanostructures self-organized from phenylethynyl thiophene with elaborated long-chain dicarboxamides
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Chiral amplification in one-dimensional helical nanostructures self-organized from phenylethynyl thiophene with elaborated long-chain dicarboxamides

Chun-Hsian Li, Kai-Chi Chang, Chia-Chen Tsou, Yikang Lan, Hsiao-Ching YangShih-Sheng Sun
Journal of Organic Chemistry, 卷.76(14), 頁碼.5524-5530
07/2011
PMID: 21615184

摘要

Organic Chemistry
A bis-phenylethynyl thiophene derivative functionalized with long-chain pyridyl biscarboxamides displayed unique helical morphology in the xerogel form via nicely complementary intermolecular interactions. The helical nanostructures visualized by TEM and AFM remarkably matched well with the computational results. Supramolecular chirality can be amplified by coassembly of a chiral conductor to bias the helical arrangement. © 2011 American Chemical Society.

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