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Construction of an inverted-capacitive deionization system utilizing pseudocapacitive materials
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Construction of an inverted-capacitive deionization system utilizing pseudocapacitive materials

Yi-Heng Tu, Ching-Fang Liu, Jeng-An WangChi-Chang Hu
Electrochemistry Communications, 卷.104, 106486
07/2019

摘要

Inverted-capacitive deionization Manganese dioxide Memory effect Polypyrrole Pseudocapacitive materials Electrochemistry
An inverted-capacitive deionization (i-CDI) cell of MnO 2 //polypyrrole-coated activated carbon (MnO 2 //PPy@AC) with pseudocapacitive characteristics enables unique salt-removal/salt-concentration capability. The salt adsorption capacity (SAC) of MnO 2 //PPy@AC highly depends on the discharging time and a high SAC of 27.6 mg·g 1 is obtained at the 60-min discharging time. The SAC retention of this unique cell is 100% after 10 charge/discharge cycles at 1.2/0 V. The “memory effect” of MnO 2 //PPy@AC is confirmed by the unchanged conductivity of the cell when the applied cell voltage is interrupted, which has been demonstrated for salt-removal and salt-concentration applications.

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https://doi.org/10.1016/j.elecom.2019.106486檢視
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