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Cyclo-E5-bridged trinuclear triple-decker complexes (E = P, As) containing a triply-bonded Mo2 unit and their isomerisation
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Cyclo-E5-bridged trinuclear triple-decker complexes (E = P, As) containing a triply-bonded Mo2 unit and their isomerisation

Meng-Wei Lee, Gábor Balázs, Stephan Reichl, Lisa Zimmermann, Manfred Scheer 和 Yi-Chou Tsai
Chemical Communications, 卷.59(75), 頁碼.11192-11195
08/2023
DOI: https://doi.org/10.1039/d3cc03282e
PMID: 37650148

摘要

Electronic Optical and Magnetic Materials Catalysis Ceramics and Composites Chemistry (all) Surfaces Coatings and Films Metals and Alloys Materials Chemistry
The reaction of the low-coordinate quadruply-bonded dimolybdenum complex Mo 2 [μ,κ 2 -PhB(N-2,6- i Pr 2 C 6 H 3 ) 2 ] 2 (1) with Cp*Fe(η 5 -E 5 ) (E = P, As) gives two trinuclear species Cp*Fe(μ 3 ,η 5:2:2 -E 5 )Mo 2 [μ,κ 2 -PhB(N-2,6- i Pr 2 C 6 H 3 ) 2 ] 2 (E = P (4) and As (5)). 4 undergoes facile isomerisation upon heating to give Cp*FeMo 2 [κ 2 -PhB(N-2,6- i Pr 2 C 6 H 3 ) 2 ](μ 3 ,κ:κ:η 2 -P 2 )[μ 3 ,κ:κ:η 3 κ-P 3 PhB(N-2,6- i Pr 2 C 6 H 3 ) 2 ] (6), where the FeMo 2 P 5 core motif displays a cubane-like structure.

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