Logo image
Back
Dalton communications. Crystal structure of [na·3thf][Fe(CO)3(SePh)3] and [n(PPh3)2][Fe(CO)3(SePh) 3]·0.5thf (thf = tetrahydrofuran): Evidence for Na+ ⋯ sePh and long-range Na+ ⋯ FeII interactions
Journal article

Dalton communications. Crystal structure of [na·3thf][Fe(CO)3(SePh)3] and [n(PPh3)2][Fe(CO)3(SePh) 3]·0.5thf (thf = tetrahydrofuran): Evidence for Na+ ⋯ sePh and long-range Na+ ⋯ FeII interactions

Wen-Feng Liaw, Chia-Huei Lai, Chen-Kang Lee, Gene-Hsiang Lee and Shie-Ming Peng
Journal of the Chemical Society, Dalton Transactions, (15), pp.2421-2422
1993
DOI: https://doi.org/10.1039/DT9930002421
Appears in  keyword about Chemistry

Abstract

Chemistry (all)
The reaction between Na[HFe(CO) 4 ] and (PhSe) 2 Yielded Na[Fe(CO) 3 (SePh) 3 ] which crystallized as [Na·3thf][Fe(CO) 3 (SePh) 3 ] in which three tetrahydrofuran (thf) molecules and the [Fe(CO) 3 (SePh) 3 ] - anion surround the sodium cation; in the corresponding crystal structure of [N(PPh 3 ) 2 ][Fe(CO) 3 -(SePh) 3 ]·0.5thf the cations and anions are discrete entities.

Metrics

1 Record Views

Details

Logo image