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Desmearing small-angle scattering data by central moment expansions of instrument resolution
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Desmearing small-angle scattering data by central moment expansions of instrument resolution

冠榮 黃, Lionel Porcar, Yuya Shinohara, Christoph U. Wildgruber, Chi-Huan Tung, Changwoo DoWei-Ren Chen
Journal of Applied Crystallography, 卷.58(4)
01/08/2025

摘要

Small-Angle Scattering;Desmearing;Central Moment Expansion;Instrument Resolution Effect;Soft Matter

This study introduces an enhanced numerical technique tailored specifically for refining 1D small-angle scattering (SAS) intensity profiles affected by smearing. Our primary objective is to address the resolution blurring commonly encountered in SAS data, particularly in systems with clearly defined correlation peaks whose spread aligns with the width of the resolution function at corresponding Q positions. Unlike previous approaches that expanded the SAS intensity using central moment expansion, the new method focuses on expanding the resolution function itself, thus eliminating artificial oscillations observed in smeared spectra due to limitations inherent in our earlier algorithm. This method is straightforward to implement, computationally efficient and consistently performs well in numerical benchmarking. To illustrate its effectiveness, we present a case study of a lamellar phase characterized by distinct peaks in its small-angle neutron scattering intensities.

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