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Desmearing two-dimensional small-angle neutron scattering data by central moment expansions
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Desmearing two-dimensional small-angle neutron scattering data by central moment expansions

Guan-Rong Huang, Chi-Huan Tung, Weijian Hua, Yifei Jin, Lionel Porcar, Yuya Shinohara, Christoph U. Wildgruber, Changwoo DoWei-Ren Chen
Journal of applied crystallography, 卷.58(5), 頁碼.1542-1552
10/2025

摘要

Chemistry Chemistry, Multidisciplinary Crystallography Physical Sciences Science & Technology
Resolution smearing is a critical challenge in the quantitative analysis of two-dimensional small-angle neutron scattering (SANS) data, particularly in studies of soft-matter flow and deformation using SANS. We present a central moment expansion technique to address smearing in anisotropic scattering spectra, offering a model-free desmearing methodology. By accounting for directional variations in resolution smearing and enhancing computational efficiency, this approach reconstructs desmeared intensity distributions from smeared experimental data. Computational benchmarks using interacting hard-sphere fluids and Gaussian chain models validate the accuracy of the method, while simulated noise analyses confirm its robustness under experimental conditions. Experimental validation using rheological SANS data from shear-induced micellar structures demonstrates the practicality and effectiveness of the proposed algorithm. The desmearing technique provides a powerful tool for advancing the quantitative analysis of anisotropic scattering patterns, enabling precise insights into the interplay between material microstructure and macroscopic flow behavior.

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