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Direct observation of the interface structure of thin YBa 2Cu3Ox film (<500 Å) deposited on SrTiO3(001) utilizing grazing incidence x-ray diffraction
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Direct observation of the interface structure of thin YBa 2Cu3Ox film (<500 Å) deposited on SrTiO3(001) utilizing grazing incidence x-ray diffraction

Tsai-Sheng Gau, Shih-Lin Chang, Hsueh-Hsing Hung, Hsueh-Hsing Hung, Chih-Hao Lee, Tung-Wuu Huang, Horng-Bor Lu, Sheng-Jenn Yang and Shu-En Hsu
Applied Physics Letters, Vol.65(13), pp.1720-1722
1994

Abstract

The structure near the interface of thin YBa <sub>2</sub> Cu <sub>3</sub> O <sub>x</sub> films (<500 Å) deposited on SrTiO <sub>3</sub> (001) with laser ablation was revealed utilizing grazing incidence x-ray diffraction. The structure consists of a layer with large crystal mosaicity just above the interface, a c-oriented tetragonal layer with lattice constants a=b=3.883±0.001 Å, and a well textured but strained orthorhombic layer with lattice constants a≅3.887 Å, b≅3.867 Å in the middle, and a thin air-contaminated top layer. The thicknesses of the differently structured layers determined from x-ray reflectivity data are 50±4.7, 20±2.2, 200±5.5, and 12.56±0.14 Å, from the interface to the top layer, respectively. Since there are no additional phases appearing in this system aside from those mentioned, we conclude that the film remains strained at a distance about 300 Å above the interface.

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