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Discontinuous precipitation leading to nano-rod intermetallic precipitates in an Al0.2Ti0.3Co1.5CrFeNi1.5 high entropy alloy results in an excellent strength-ductility combination
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Discontinuous precipitation leading to nano-rod intermetallic precipitates in an Al0.2Ti0.3Co1.5CrFeNi1.5 high entropy alloy results in an excellent strength-ductility combination

S. Dasari, Y.-J. Chang, A. Jagetia, V. Soni, A. Sharma, B. Gwalani, S. Gorsse, A.-C. YehR. Banerjee
Materials Science and Engineering A, 140551
2020

摘要

Complex concentrated alloys Discontinuous precipitation High entropy alloys Intermetallic precipitates Mechanical properties Materials Science (all) Condensed Matter Physics Mechanics of Materials Mechanical Engineering
The phenomenon of discontinuous precipitation (DP) leading to the formation of nano-rod FCC (γ) + L12 (γ’) colonies, has been typically considered deleterious for mechanical properties. However, the present study shows clear evidence that substantially large fractions of FCC + nano-rod L12 microstructure within a thermo-mechanically processed high entropy alloys (HEA) or complex concentrated alloys (CCA) of composition Al <sub>0.2</sub> Ti <sub>0.3</sub> Co <sub>1.5</sub> CrFeNi <sub>1.5</sub> , formed via recrystallization coupled with discontinuous precipitation, can lead to an excellent combination of room temperature strength and ductility. The extent of thermomechanical processing can be engineered to modify the phase transformation pathway from homogenous L1 <sub>2</sub> precipitation to discontinuous L1 <sub>2</sub> precipitation in the same HEA. This predominantly FCC + nano-rod L1 <sub>2</sub> microstructure exhibits a yield stress ~1.4 GPa, ultimate tensile strength ~1.6 GPa, and tensile ductility of ~14%, making it one of the best combinations of room temperature tensile properties for FCC-based HEAs, that have been reported to date, as well as better than current generation wrought nickel base superalloys. A high yield strength of the order of ~1 GPa is also retained to a temperature of 500 °C in this alloy. However, at higher temperatures (>550 °C), the DP microstructures exhibit a rapid decline in strength and become less competitive as compared to microstructures consisting of homogeneously precipitated L1 <sub>2</sub> within the FCC matrix.

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https://doi.org/10.1016/j.msea.2020.140551檢視
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