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Effects of physical and chemical activations on the performance of biochar applied in supercapacitors
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Effects of physical and chemical activations on the performance of biochar applied in supercapacitors

Chung-Hsuan Hsiao, Shivam Gupta, Chi-Young LeeNyan-Hwa Tai
Applied Surface Science, 卷.610, 155560
02/2023

摘要

Activation method Asymmetric supercapacitor Biomass materials Hierarchical activated carbon Oyster shell powder Chemistry (all) Condensed Matter Physics Physics and Astronomy (all) Surfaces and Interfaces Surfaces Coatings and Films
Recently, there has been a growing concern for environmental protection. Herein, an economical, sustainable, and green method for synthesizing activated carbon from waste using Sapindus peels and oyster shell powder is reported. Oyster shell powder decomposes into CO 2 at high temperatures and can be used as a physical activator. In this study, we discuss the difference between physical, chemical, and hybrid activation. Through proper treatment, the original specific surface area of 12.8 m 2 g −1 for Sapindus peel biochar was increased to 1175–1537 m 2 g −1 . In addition, activated carbons rich in 4 nm mesopores can be obtained by simple physical activation with oyster shell powder. In applications, the prepared electrodes showed a high specific capacitance of 258.1 F g −1 at 5 mV s −1 . The assembled supercapacitor also exhibited excellent electrochemical performance with a capacitance retention of 81.9 % after 5000 test cycles and a coulombic efficiency close to 100 % during the test.

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