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Efficient total syntheses of (±)protolichesterinic acid and (±)rocellaric acid via tungsten-π-allyl complexes
Journal article   Peer reviewed

Efficient total syntheses of (±)protolichesterinic acid and (±)rocellaric acid via tungsten-π-allyl complexes

Ming-Jung Chen and Rai-Shung Liu
Tetrahedron Letters, Vol.39(51), pp.9465-9468
17/12/1998

Abstract

Total syntheses of racemic protolichesterinic acid (1) and rocellaric acid (2) were achieved with the use of tungsten-π-allyl complex in the key step. In this synthetic route, compounds 1 and 2 were prepared in four and six steps respectively starting from readily available chloropropargyl derivatives.

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