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Emergent quasi-two-dimensional metallic state derived from the Mott-insulator framework
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Emergent quasi-two-dimensional metallic state derived from the Mott-insulator framework

P. -C. Chiang, S. C. Lin, C. -Y. Chiang, C. -S. Ku, S. W. Huang, J. M. Lee, Y. -D. Chuang, H. J. Lin, Y. F. Liao, C-M. Cheng, …
Physical review B, 卷.107(7), 075104
02/02/2023
Web of Science ID: WOS:000994364500004

摘要

Materials Science, Multidisciplinary Physics, Applied Physics, Condensed Matter Science & Technology Materials Science Physical Sciences Physics Technology
Recent quasi-two-dimensional (quasi-2D) systems with judicious exploitation of the atomic monolayer or few-layer architecture exhibit unprecedented physical properties that challenge the conventional wisdom on condensed matter physics. Here we show that the infinite layer SrCuO2 (SCO), a topical cuprate Mott insulator in bulk form, can manifest an unexpected metallic state in the quasi-2D limit when SCO is grown on TiO2terminated SrTiO3 (STO) substrates. The sheet resistance does not conform to Landau's Fermi liquid paradigm. Hard x-ray core-level photoemission spectra demonstrate a definitive Fermi level that resembles the hole doped metal. Soft x-ray absorption spectroscopy also reveals features analogous to those of a hole doped Mott insulator. Based on these results, we conclude that the hole doping does not occur at the interfaces between SCO and STO; instead, it comes from the transient layers between the chain-type and the planar-type structures within the SCO slab. The present work reveals a metallic state in the infinite layer SCO and invites further examination to elucidate the spatial extent of this state.

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